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71.
目的应用实时三维超声心动图探讨肺源性心脏病患者右心室收缩功能的价值,比较右心造影对测值的影响。方法选择肺源性心脏病代偿组、失代偿组、正常对照组各20例分别进行造影前、后实时三维超声的采集成像,计算右心室舒张末容积(RVEDV)、右心室每博输出量(RVSV)和右心室射血分数(RVEF),并根据心内膜是否清晰可辨分为心内膜边界清晰者、心内膜边界欠清晰者,比较两者三维超声参数的组间差异。结果代偿组、失代偿组RVEDV较对照组均明显增加,RVEF值减低(均P<0.01),代偿组与对照组RVSV差异无统计学意义(P>0.05),但失代偿组RVSV与代偿组、对照组差异有统计学意义(P<0.05);失代偿组RVEDV较代偿组明显增大,RVEF明显减低(均P<0.01)。心内膜边界欠清晰者造影后较造影前RVEDV、RVEF差异均有统计学意义(均P<0.05)。结论实时三维超声能够客观地反映肺源性心脏病代偿期与失代偿期右心室收缩功能的变化,右心声学造影改善了心内膜边界的可识别性,提高了右心室收缩功能测值的可靠性。 相似文献
72.
In this paper, the super-linearly and quadratically convergent strong sub-feasible method [J.L. Li, J.B. Jian, A superlinearly and quadratically convergent strongly subfeasible method for nonlinear inequality constrained optimization, OR Transactions, 7 (2) (2003) 21-34] for nonlinear inequality constrained optimization is improved, such that the iterative points can get into the feasible region after a finite number of iterations. As a result, a strict restricted condition can be overcome. Another two contributions of this paper are that a new bidirectional Armijo line search is presented and a lot of numerical comparison results are reported. 相似文献
73.
A complete assignment of all resonances of a small organic molecule is a prerequisite for a structure determination using NMR spectroscopy. This is conventionally obtained using a well‐established strategy based on COSY, HMQC and HMBC spectra. In case of phycocyanobilin (PCB) in HMPT this strategy was unsuccessful due to the symmetry of the molecule and extreme signal overlap. Since 13C and 15N labeled material was available, an alternative strategy for resonance assignment was used. Triple resonance experiments derived from experiments conventionally performed for proteins are sensitive and easy to analyze. Their application led to a complete and unambiguous assignment using three types of experiments. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
74.
We have performed the direct measurements of 13C magnetic shielding for pure liquid TMS, solution of 1% TMS in CDCl3 and solid fullerene. The measurements were carried out in spherical ampoules exploring the relation between the resonance frequencies, shielding constants and magnetic moments of 13C and 3He nuclei. Next the 13C shielding constants of glycine, hexamethylbenzene and adamantane were established on the basis of appropriate chemical shifts measured in the solid state. All the new results are free from susceptibility effects and can be recommended as the reference standards of 13C shielding scale in the magic angle spinning NMR experiments. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
75.
Finite element Galerkin approximations to a class of nonlinear and nonlocal parabolic problems 下载免费PDF全文
Nisha Sharma Morrakot Khebchareon Kapil Sharma Amiya K. Pani 《Numerical Methods for Partial Differential Equations》2016,32(4):1232-1264
In this article, a finite element Galerkin method is applied to a general class of nonlinear and nonlocal parabolic problems. Based on an exponential weight function, new a priori bounds which are valid for uniform in time are derived. As a result, existence of an attractor is proved for the problem with nonhomogeneous right hand side which is independent of time. In particular, when the forcing function is zero or decays exponentially, it is shown that solution has exponential decay property which improves even earlier results in one dimensional problems. For the semidiscrete method, global existence of a unique discrete solution is derived and it is shown that the discrete problem has an attractor. Moreover, optimal error estimates are derived in both and ‐norms with later estimate is a new result in this context. For completely discrete scheme, backward Euler method with its linearized version is discussed and existence of a unique discrete solution is established. Further, optimal estimates in ‐norm are proved for fully discrete schemes. Finally, several numerical experiments are conducted to confirm our theoretical findings. © 2016 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 32: 1232–1264, 2016 相似文献
76.
In this paper, a theoretical model was established to determine the contact angle by introducing a new defined effective capillary radius into the Lucas–Washburn equation. Based on the theoretical model, capillary rise experiments of water imbibed by different glass beads were carried out to measure the contact angle; the results were similar to the available data published in the literature. In addition, the model was modified to take account of the dynamic contact angle, according to the experimental data. The influence of the dynamic contact angle on the movement of the spontaneous imbibition was studied. 相似文献
77.
《高分子科学杂志,C辑:聚合物评论》2013,53(2):99-124
Thermally stimulated recovery (TSR) is a non‐conventional mechanical spectroscopy technique that allows to analyse in detail the relaxation processes of polymeric systems in the low frequency region. This work reviews the main aspects and potentialities of this technique. The different kinds of TSR experiments that can be performed, global and thermal sampling (TS) experiments, are described and illustrated with several examples. Also, the different methods for the determination of the thermokinetic parameters (activation energy and pre‐exponential factor) of the thermal sampling (TS) procedure are explained and compared. In this context, the compensation phenomenon, which always appears in TSR results when the studies are performed in the glass transition region of a given system, is discussed. Examples of the application of this technique to different polymeric systems during the last 20 years are provided. An emphasis will be made on the analysis of the effect of crystallinity degree and crosslink density on the TSR response. A comparison between the results (characteristic times and activation energies) obtained by different techniques, namely TSR, dynamic mechanical analysis (DMA), and differential scanning calorimetry (DSC), is made. 相似文献
78.
课程体系是人才培养的载体。为了更好地培养拔尖创新人才,南京大学化学国家级实验教学示范中心依据化学学科的特点和发展趋势,以科学内容的内在联系和研究规律为主线构建了“化学实验基础?化学合成与表征+化学原理与测量?化学功能分子实验+化学生物学综合实验+基于项目的研究实验”实验课程新体系,按照一流课程建设要求(高阶性、创新性和挑战度)对实验教学内容进行了优化,并建立起与之相适应的实验教学平台。新课程体系综合考虑了化学一级学科的整体性和关联学科的交叉性,在南京大学化学化工学院“拔尖计划”和“强基计划”学生中实施,教学效果显著。 相似文献
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